OK first things first, You dont have to use PostCatagorie as your model name. Laravel features a pretty good pluralization class and can quite happily deal with Category or PostCategorie. Additionally, if you just call pc_id
category_id (assuming a table name of category) you wont have to define any foreign keys which will make life a bit simpler until you get to grips with the basics.
When you create any kind of object (e.g $post) you can check if its relations are attached using dd($post);
you can drill down further into these relations with:
echo '<pre>';
print_r($post);
echo '</pre>;
This together will allow you to see if what you are trying to do is actually working and view the structure of your result object.
I'm not entirely sure what you mean by "I cant add categories id to another table", and you seem to be saving the data ok... so I'll skip that bit. Please clarify the question if you need more info.
Once you have got the relationships set up and got some data in there you would have to load the two models together like so to get an object with the attached relationship:
$post = Post::with('Category')->find(5);
You will then be able to access your category object as $post->Category
and from there any of its properties, e.g. $post->Category->id