Valid values are only from 0% to 100%
https://developer.mozilla.org/en-US/docs/Web/CSS/filter#saturate()
The same is true for HSL in CSS
http://www.w3.org/TR/css3-color/#hsl-color
You just have to find out the scale PhotoShop uses and adjust accordingly.
If you're using a preprocessor like SASS or LESS, you could do it there.
So if PhotoShop goes from -100% to 100%, you could do (100% + $val)/2
(You could also use CSS calc, but this case is better for a preprocessor, or even manual calculation - just be sure to comment!)