Make a string. Then set it as the text of the label.
For example:
from Tkinter import * # Python 3.x: from tkinter import *
from ttk import * # Python 3.x: from tkinter.ttk import *
D = {'d1': {'a':'1'}, 'd2': {'b':'2'}, 'd3': {'c':'3'}}
root = Tk()
lb = Label(root, text='')
lb['text'] = '\n'.join('{} {}'.format(k, d) for k, d in D.items()) # <---
# OR lb.config(text=....)
# OR lb.configure(text=...)
lb.pack()
root.mainloop()