The SQL in the link (Number of working days between two dates) translated for SSRS: Hopefully this will give you a good place to start. Type this into the expression for the textbox.
=(DateDiff(DateInterval.day,Parameters!STARTDATE.Value,Parameters!ENDDATE.Value)+1)
-(DateDiff(DateInterval.WeekOfYear,Parameters!STARTDATE.Value,Parameters!ENDDATE.Value)*2)
-(iif(Weekday(Parameters!STARTDATE.Value) = 7,1,0)
-(iif(Weekday(Parameters!ENDDATE.Value) = 6,1,0))-1)