First of all you should check if you restart your IIS server or not after changing php.ini file.
If it doesn't help, you can check PHP settings for the IIS, open index.php file and put this code in the beginning:
<?php
phpinfo();
exit;
After that, refresh your website. You'll see all PHP settings for IIS. Here you can find the path to php.ini file and check is that your file you were changed.
Hope it helps.