OK, it seems like one error was based on the way I indicated the path-to-folder. Using "C:\\Folder\\folder\\file" to set the directory seems not to work properly? However, using "C:/Folder/folder/file" seems to do the job.
Nevertheless, I keep on having continuous issues with the ff-files on a network (e.g., they do not load after saving them).
SaveRDS and ReadRDS seem to do a great job for quickly saving and reading in large files (which are also compressed). So thanks for that Jan!