You access the value in a hashtable by using the get(key) method. In your case you could do the following:
Character one=(char) myStack.pop();
Character two=(char) myStack.pop();
String str1 = Character.toString(one);
String str2 = Character.toString(two);
double first=Double.parseDouble(numbers.get(str1));
double second=Double.parseDouble(numbers.get(str2));
double temp=first+second;
myStack.push(temp);
Since your hashtable key is a String you need to use a String in the get() method.