NM I figured it out...
DataGridViewComboBoxColumn dgcShipType = new DataGridViewComboBoxColumn();
...
//Column SHIP-TO COMBOBOX
dgcShipType.ReadOnly = false;
dgcShipType.AutoComplete = false;
dgcShipType.DisplayStyleForCurrentCellOnly = true;
dgcShipType.DropDownWidth = 100;
dgcShipType.Width = 110;
dgcShipType.HeaderText = "ShipType";
dgcShipType.Items.AddRange(new object[] { "GROUND", "LOCAL PATIENT", "3-DAY UPS", "2-DAY SERVICE", "PRIORITY OVERNT", "EARLY AM", "WILL CALL" });
dgcShipType.Name = "colComboShip";
dgcShipType.MaxDropDownItems = 7;
dgcShipType.Resizable = System.Windows.Forms.DataGridViewTriState.True;
dgcShipType.SortMode = System.Windows.Forms.DataGridViewColumnSortMode.Automatic;
dgcShipType.DefaultCellStyle.NullValue = "GROUND"; //sets the default display value
dgcShipType.DisplayIndex = 5;
//
...
this.dgvMasterPrinting.Rows.Add(...