If you don't choose at installation to make Canopy your default python, you will need to add its executable on the path if you want it to be invoked when you start python or ipython as opposed to your system python. The python executable in Canopy should be at ~/Library/Enthought/Canopy_**bit/User/bin/python
where ** is 32 or 64 depending on the architecture you chose.
You can modify your .bash_profile and add ~/Library/Enthought/Canopy_**bit/User/bin/
first on your PATH or run the following from your terminal:
source ~/Library/Enthought/Canopy_**bit/User/bin/activate
for this to be true until you close your terminal.
HTH,