I believe permalinks are determined by settings + post file names, not settings + post titles.
So you should have files names like
_posts\2014-04-12-hello-world.md
instead of
_posts\2014-04-12-je-každoročně-tak-veliký.md
Inside the post, you can still use post title in Czech.
Permalinks' documentation is here, note if you have Czech categories and you use them in permalinks, you will still get into trouble, so it's better to avoid Czech categories in permalinks.