Have you tried the following overload:
AddJob() - Inserts a new (generically named) print job, whose content is a Byte array, into the queue.
Some Sample code as obtained from MSDN is as follows
// Create the printer server and print queue objects
LocalPrintServer localPrintServer = new LocalPrintServer();
PrintQueue defaultPrintQueue = LocalPrintServer.GetDefaultPrintQueue();
// Call AddJob
PrintSystemJobInfo myPrintJob = defaultPrintQueue.AddJob();
// Write a Byte buffer to the JobStream and close the stream
Stream myStream = myPrintJob.JobStream;
Byte[] myByteBuffer = UnicodeEncoding.Unicode.GetBytes("This is a test string for the print job stream.");
myStream.Write(myByteBuffer, 0, myByteBuffer.Length);
myStream.Close();