You did read http://docwiki.embarcadero.com/Libraries/XE2/en/System.Classes.TStringList.Duplicates , didn't you ?
Then you missed the most repeated word there - "sorted"
channelList.Sorted := true
var F: TField;
channelList := TStringList.Create;
channelList.Sorted := True;
channelList.Duplicates := dupIgnore;
try
dataset.First;
F := dataset.FieldByName('CHANNEL_INT');
while not dataset.EOF do
begin
channelList.Add(F.AsString);
dataset.Next;
end;