Following the same steps, this problem happens for me as well.
If I then add a reference to System.Data, the error goes away and the code compiles. Looking at your screenshot, it appears that you do not have a reference to System.Data. Under the Project menu, choose Edit References, make sure the All tab is open, and then put a checkmark next to System.Data.
I am using the recently-released Xamarin.iOS 6.4. I don't remember needing to do this step before, which suggests that perhaps previous versions of Xamarin.iOS included the reference to System.Data by default. I've got a little uncertainty here yet that needs to be eliminated.
I hope this helps.