Great question!
The modified attribute relates only to the individual attendee in the order. So, it won't be triggered by the account wide profile changes for that respective user. However, if a user logs in to Eventbrite and changes the information that specifically relates to this event (example: they change the spelling on their last name for this specific order).
Alternatively, you can actually use /event_list_attendees and set "display_full_barcodes" to "true" to see the status of the barcodes. When the barcode is used, you'll know that someone has been scanned in.
If you come up with a cool hack, then we'd love to check it out!
Hope that helps!