In your case you need weighted average here, something like this in the Total row:
=Sum(Fields!numOfStudents.Value * Fields!avgGpa.Value)
/ Sum(Fields!numOfStudents.Value)
You can see I'm creating the expression Fields!numOfStudents.Value * Fields!avgGpa.Value
for each row, summing that, then dividing by the total students.
In your case this would give (89 * 3.68 + 107 * 3.23 + 85 * 3.75) / (89 + 107 + 85)
, i.e. 3.53
, which seems about correct.