Here is a guide you can use to set up your own SMTP server. Assuming you own "from.com" this will resolve your issue.
Have a look at the MSDN Documentation
If you need to send email from many different domains you can configure virtual SMTP servers for each domain. Have a look at this article.
If you do not own the domains that you are attempting to send mail from then it will look like you are spoofing the sender address.