You are looking for the function ord
which is a built-in function that
Returns the integer ordinal of a one-character string.
So for instance, you can do:
my_file = open("file_containing_encrypted_message")
data = my_file.read()
to read in the encrypted contents.
Then, you can iterate over each character doing
char_val = ord(each_character)
block_decode(char_val)