You can verify the accuracy of the estimated nonlinear lens distortion parameters independently of pose. Capture images of straight edges (e.g. a plumb line, or a laser stripe on a flat surface) spanning the field of view (an easy way to span the FOV is to rotate the camera keeping the plumb line fixed, then add all the images). Pick points on said line images, undistort their coordinates, fit mathematical lines, compute error.
For the linear part, you can also capture images of multiple planar rigs at a known relative pose, either moving one planar target with a repeatable/accurate rig (e.g. a turntable), or mounting multiple planar targets at known angles from each other (e.g. three planes at 90 deg from each other).
As always, a compromise is in order between accuracy requirements and budget. With enough money and a friendly machine shop nearby you can let your fantasy run wild with rig geometry. I had once a dodecahedron about the size of a grapefruit, machined out of white plastic to 1/20 mm spec. Used it to calibrate the pose of a camera on the end effector of a robotic arm, moving it on a sphere around a fixed point. The dodecahedron has really nice properties in regard to occlusion angles. Needless to say, it's all patented.