Your expression has two division operations at the same level (no parentheses). Assuming that division associates left-to-right, then the expression should be interpreted as
(10 / (2 - 4)) / 5
This should then turn into the following in postfix notation:
10 2 4 - / 5 /
The postfix you ended up with would correspond to the ordering:
10 / ((2 - 4) / 5)
Generating the reverse Polish from a parse tree should clear up the problem, assuming the parse tree is generated correctly from the infix expression.