http://www.example.com/category/বাংলা
isn't a URL; URLs can only contain ASCII characters. This is an IRI.
http://www.example.com/category/%E0%A6%AC%E0%A6%BE%E0%A6%82%E0%A6%B2%E0%A6%BE
is the URI representation of that IRI. They are otherwise equivalent. A browser may display the ‘pretty’ IRI version in the user interface, but put the URI version on the clipboard so that you can paste it into other tools that don't support IRI.
The 404 address you pasted translates to:
/category/স্নায়ুবিদ্য�
where the last character is a � because it is an invalid, truncated UTF-8 sequence. (This is probably why the request failed.) Someone may have mis-pasted a partial URI here.