Is this what you want? I made up a slightly larger dummy data set of 'area' to make it easier to see how the code worked when I tried it out.
# create 400 rows of area data
set.seed(123)
df <- data.frame(area = round(rnorm(400, mean = 1000000, sd = 100000)))
# "sample numbers repeats after 200" -> add a sample nr 1-200, 1-200
df$sample_nr <- 1:200
# create a factor which cuts the vector of sample_nr into pieces of length 16, 24, 16, 24...
# repeat to a total length of the pieces is 200
# i.e. 5 repeats of (16, 24)
grp <- cut(df$sample_nr, breaks = c(-Inf, cumsum(rep(c(16, 24), 5))))
# add a numeric version of the chunks to data frame
# this number indicates the model from which coefficients will be used
# row 1-16 (16 rows): model 1; row 17-40 (24 rows): model 2;
# row 41-56 (16 rows): model 3; and so on.
df$mod <- as.numeric(grp)
# read coefficients
coefs <- read.table(text = "intercept beta_conc
1 -108589.2726 846.0713372
2 -49653.18701 811.3982918
3 -102598.6252 832.6419926
4 -72607.4017 727.0765558
5 54224.28878 391.256075
6 -42357.45407 357.0845661
7 -34171.92228 367.3962888
8 -9332.569856 289.8631555
9 -7376.448899 335.7047756
10 -37704.92277 359.1457617", header = TRUE)
# add model number
coefs$mod <- rownames(coefs)
head(df)
head(coefs)
# join area data and coefficients by model number
# (use 'join' instead of merge to avoid sorting)
library(plyr)
df2 <- join(df, coefs)
# calculate conc from area and model coefficients
# area = intercept + beta_conc * conc
# conc = (area - intercept) / beta_conc
df2$conc <- (df2$area - df2$intercept) / df2$beta_conc
head(df2, 41)