With Firefox 29 the support for Sass and LESS files was introduced.
Taken from https://hacks.mozilla.org/2014/02/live-editing-sass-and-less-in-the-firefox-developer-tools/
You have to right-click in the Rules section and activate Show original sources option:
Now CSS rule links will show the location in the original file, and clicking these links will take you to the source in the Style Editor.
From there you can go on to the Styles Editor and edit your Sass/LESS file. Functionality needs Source Maps enabled!