"Increment i everytime we decide not to visit a vertex because
it has already been visited."
I am quite unclear about what you are trying to do here.
Rather then this, how about this:
Perform DFS and count number of back edges.
A back edge is an edge that is from a node to itself (selfloop) or one of its
ancestor in the tree produced by DFS.
If number of back edges ==1 then unicycle else not.
To count number of back edges, follow this algorithm.
To detect a back edge, we can keep track of vertices currently in recursion stack of
function for DFS traversal. If we reach a vertex that is already in the recursion stack,
then there is a cycle in the tree. The edge that connects current vertex to the
vertex in the recursion stack is back edge