I do not think you should be creating the NavigationService the way you are doing. Also if you want to enable navigation all this should be done in a Frame
<Frame x:Name="_mainFrame" />
Then you could do something like
_mainFrame.NavigationService.Navigate(new Uri("EnlargedScreenCap.xaml", UriKind.Relative));
Without the double slashes in front.
Checkout this article. http://paulstovell.com/blog/wpf-navigation
Hope it helps