Get the options, iterate and check if they are selected, and add the values to an array
var select = document.getElementById('CK_Expertise'),
options = select.getElementsByTagName('option'),
values = [];
for (var i=options.length; i--;) {
if (options[i].selected) values.push(options[i].value)
}
console.log(values)
or being a little more fancy
var select = document.getElementById('CK_Expertise'),
values = Array.prototype.filter.call(select.options, function(el) {
return el.selected;
}).map(function(el) {
return el.value;
});
console.log(values)