I refer to the comment-question of Vikas Prasad: "@ReeCube can I achieve all my requirements for the program trying JSON or XML. If yes can you point me to specific tutorials. I have no idea about these two. Also which one to prefer among both?"
JSON or XML are just the way how you transfer the data and how you read them after, you need php and c# to use JSON or XML. I prefer JSON but im not sure how well it's working on C#, I've never tested it.
Here you can find an JSON API for C#.
But first you should add JSON for your PHP-server. On PHP, JSON is very easy to use, there is an json_encode and json_decode function. In your case, you just need the json_encode function, because on the server side, you just want to generate the JSON for the client. How to use json_encode is very well supported by Google and the PHP documentation, but if you have questions, just ask in a comment.
Here is a little example:
<?php
$arr = array('a' => 1, 'b' => 2, 'c' => 3, 'd' => 4, 'e' => 5);
echo json_encode($arr);
?>