I don't know about your url scheme for your application, but single % encoded values are valid in a url in place of the chars they represent, and should be decoded by the server, what you are seeing is what I would expect. If you need to pass url reserved characters as a value and not have them decoded as part of the url, you will need to double % encode them. It's a fairly common practice, the complexity added to the client & server will not be that much, and a short comment will do rightly.
In short, If you need to pass url chars, double % encode them, it's fine.