I finally found the registry documentation for Help Viewer 2.0 at:
http://msdn.microsoft.com/en-us/library/hh500508.aspx
I solved the problem by Editing:
HKEY_LOCAL_MACHINE\SOFTWARE\Wow6432Node\Microsoft\Help\v2.0\Catalogs\VisualStudio11, setting the Key, LoactionPath, to the Value, C:\ProgramData\Microsoft\HelpLibrary2\Catalogs\VisualStudio11
Note that the .mshc, .mshi, .metadata files are located at: C:\ProgramData\Microsoft\HelpLibrary2\Catalogs\VisualStudio11\ContentStore\en-US