All ZigBee radios should interoperate -- you just need to make sure they are configured to join to each other. With XBee modules, be sure to set ATZS to 2 so the radios form and try to join a true ZigBee network. The default setting of 0 is for non-ZigBee networks.
To have modules join to each other, you'll need to know the PAN ID and possibly link key used to secure the network.
Once you start communicating via ZigBee, expect to use these modules in an API frame mode, where you need to set address information (destination node, source/destination endpoint, cluster) in the headers.