The XML namespace that you have used will only work with the Ribbon Control library that is downloaded separately from the .NET Framework... I believe that you can still download that version from the Microsoft Ribbon for WPF October 2010 page on MSDN. This was the only way to use the Ribbon Control library before it was included in the Framework version 4.5.
If you are using the Ribbon Control library that is included with the .NET Framework, then you should use the following XML namespace:
xmlns:Ribbon="clr-namespace:System.Windows.Controls.Ribbon;assembly=System.Windows.Controls.Ribbon"