Tomcat 8 does not have a stable release yet and Solr has not been tested with it. There may be some incompatibilities. Please try with Tomcat 7 to rule out issues with Tomcat 8.
Moreover, the last release of SolrNet was made about 2 years ago - I am not sure if it will work well with the latest release of Solr. I think you should use SolrJ if possible. Otherwise, just post the Solr docs as XML.