SharpZipLib uses PkzipClassic and AES.
if I can be sure no one is able to unzip without knowing the password
If you use AES with a key size of 128 or higher, then yes, you can be sure. Please see this article:
http://www.eetimes.com/document.asp?doc_id=1279619
According to that article, it would take 3.31 * 1056 years to crack a 256-bit key.