Simply order by bsect and display different optgroups dynamically
<?php
$query = $mysqli->query("SELECT DISTINCT bsect, bname AS Name FROM kjv ORDER BY bsect");
?>
<select name="book">
<?php
$i = 1;
$bsect = "";
while($option = $query->fetch_object()){
if($bsect != $option->bsect) {
$bsect = $option->bsect;
echo "<optgroup label='{$bsect}'>";
}
else if($i==40) echo "<optgroup label='New Testament'>";
echo "<option value='$i'>".$option->Name."</option>";
$i++;
}
?>
Of course, then your books may be out of order. So what you would want to do is add a book-order column (border) that stores a number defining how to order the books in a given group, e.g.
ALTER TABLE kjy
ADD COLUMN border INT U?NSIGNED NOT NULL DEFAULT 0;
Then you can update the data to have the proper book order and do a query like this:
SELECT DISTINCT bsect, bname AS Name FROM kjv ORDER BY bsect, border;
Of course, this being the Bible, you aren't going to be adding books, so you can probably just define a static Book ID that defines the ordinality of each book. Then you could just sort by ID and know that "Old" and "New" books are coming out in the right order.
ALTER TABLE kjy
ADD COLUMN id INT UNSIGNED NOT NULL PRIMARY KEY BEFORE (bname);