From the Sprite Kit Programming Guide (emphasis added):
Sprite Kit also has a standard rotation convention. Figure 4-2 shows the polar coordinate convention. An angle of 0 radians specifies the positive x axis. A positive angle is in the counterclockwise direction.
In this coordinate system, an angle of zero radians pointing to the right is correct. If you want to use a system in which a zero angle is straight up (along positive y axis) and increase clockwise, you'll want to transform your angles before converting them to vectors.