I'm not entirely sure what the problem is here. I took a screenshot of the Reminders app, and measured the blue color as 26, 173, 248 in Decimal mode. Then I went to my app's storyboard and set the view background color to 26, 173, 248 using the sliders. I ran my app on the phone and took a screenshot of it. Digital Color Meter reads 26/173/248 on my app as I would expect.
If you're using UIColor, you can use Percentage mode on Digital Color Meter to give you the correct values. For me, that blue color reads as 10%, 68%, 97%, so I used this code:
[UIColor colorWithRed:.1f green:.68f blue:.97f alpha:1];
I set that as my view background color in code, and running it I can't see any difference between it and the label background I set using the sliders on the storyboard.