xmlns
is the default namespace, xmlpoke require a prefix for xpath parsing:
<xmlpoke
file="${ConfigPath}\sqlmap.config"
xpath="/iba:sqlMapConfig/iba:database/iba:dataSource/@connectionString"
value="${ConnectionString}">
<namespaces>
<namespace prefix="iba" uri="http://ibatis.apache.org/dataMapper" />
</namespaces>
</xmlpoke>