There's no out of the box template for Office 2007 in Visual Studio 2013, but the addin will run fine in Office 2007.
Your project will have the Object Model for Office 2013 so while you can use it in previous versions of Office, you need to be careful not to call methods that aren't available in the earlier versions. For example in Outlook 2013 there is an inline reply so if you try to call that method in Outlook 2007 it will throw an exception.
If you're just looking to use the newer Visual Studio IDE for Office 2007 development then you can remove the 2013 Office references and add the 2007 references and you won't see any new methods as outlined above.
Edit: Not that you'd want to do this, but if you wanted to use the newer object model from 2007 without pulling in the interop library for 2013 you can actually call those newer methods dynamically and specify non existing delegate types by using Delegate.CreateDelegate
, if anything it's pretty neat.