Try:
set songAlias to alias (POSIX file "/Users/paul/tmp/Music4/My Bloody Valentine - m b v - 2013 [FLAC][24-96][WEB]/09 Wonder 2.flac")
tell application "iTunes"
set new_playlist to get first user playlist whose id is 20721
set nexttrack to add songAlias to new_playlist
set trackname to name of nexttrack
end tell