MacRuby isn't currently compatible with 10.9, not just because of the garbage collector, but due to changes in the Objective-C runtime, LLVM, and Xcode. There is a thread (titled "Mavericks and Macruby") going on right now on the macruby-devel mailing list about these issues. Joshua Ballanco's message especially sheds a lot of light on what it would take to keep MacRuby going.
You can still use the garbage collector by setting GCC_ENABLE_OBJC_GC = supported
in Xcode; but as I said, it won't make MacRuby actually usable (yet).