I didn't know you could do this but I did some googling and apparently it is possible as mentioned in this article:
http://weblogs.asp.net/imranbaloch/archive/2010/04/05/reading-all-users-session.aspx
I found the link from this Stack Overflow question: List all active ASP.NET Sessions
Once you have the list I'm assuming the code will also allow you to edit the list... but that might require some more research and trial/error...