There is no straight forward way to do this in Python 2.7, instead you can create a new list without the first element and first element alone and unpack them into respective variables.
data = ['a','b','c']
a, b = data[0], data[1:]
print a, b
Output
a ['b', 'c']
This solution will still work, even if the RHS has only one element
data = ['a']
a, b = data[0], data[1:]
print a, b
Output
a []