You will need adapt your existent database and classes to be like the Users classes of Spring Social, and then you can reuse your users data information.
You can use Spring Social with/or Spring Security without full knowedge in another's Spring frameworks like MVC or Spring Data, however some important concepts like IoC and DI are needed to understand what you are doing.
I'll recommend you one of the bests materials I found in the web about this subject. These tutorials was written by Petri Kainulainen, he also wrote a book about Spring Data. I full agreed with all his words about this application architecture.
He also made his project available in github, so you can clone his project and learn more about this subject.
I hope this can help you, Cheers!