I have been having issues symbolicating with xcode 5 as well
so I resorted to symbolicating my symbols manually using atos.
atos -arch armv7 -o myApp.app/myApp 0x178e9e
--
Warning: /usr/bin/atos is moving and will be removed from a future OS X release.
It is now available in the Xcode developer tools to be invoked via: `xcrun atos`
To silence this warning, pass the '-d' command-line flag to this tool.
--
AFJSONEncode (in myApp) + 434
the warning looked interesting so i decided to try xcrun atos
xcrun atos -arch armv7 -o myApp.app/myApp 0x178e9e
___lldb_unnamed_function6926$$myApp (in myApp) + 434
which is giving me an unnamed function.
so my guess is that Xcode 5 is using xcrun atos, which has a bug.
using atos did help me diagnose the problem and patch a fix. I do not have Xcode 4 installed. perhaps you can verify if Xcode 4 produces the same results as atos? I followed the instructions in this question
I'm in a good mind to write a script to symbolicate crash logs :/