You can use string.Split method to split string delimited by the specified characters:
string fileText = readFile.ReadToEnd();
string[] substrings = fileText.Split(',');
Then you can access each substring by an array index, for example:
textBlock1.Text = substrings[0];
textBlock2.Text = substrings[1];
Note: It would be better to check if substrings array have at least those two elements.