You are getting a FileNotFoundException because the file does not exist on the disk, if you are trying to create the file in code use the following:
File newFile = new File(newPath+"connect.ini");
newFile.createNewFile();
the createNewFile() method on Java's File class will create a file if it doesn't exist, then you can feel free to use a FileReader or FileWriter to work with the newly created (but blank) file.