I have recompiled the Graphviz4Net with the necessary changes. The official compiled version has not implemented and compiled the bug fix.
You can download the version I compiled here. PS.: Host removed file and i do not have it available atm.
It can now generate the code Label=< in dot code
Example of syntax
var newBlockSubgraph = new SubGraph<State> { Label = "<<b>Hello World</b>>" };