No, not guaranteed. It may work with some codec/container combination where frame-rate is static. avi, h264 raw (annex-b) and yuv4mpeg come to mind. But other containers like flv, mp4, ts, have a PTS/DTS (or CTS) for EVERY frame. The source could be variable frame rate, or frames could have be dropped at some point during processing due to bandwidth. Also some codecs will remove duplicate frames.
So unless you created the file yourself. Do not trust it. There is no guaranteed way to look at a frame and know its 'index' except start at the beginning and count.
Your method, MAY be good enough for most files however.