Azure Active Directory does not support the LDAP protocol so you won't be able to use .NET's System.DirectoryService classes. The AAD service uses something called the Graph API to query directory data. This is a REST based web API.
http://msdn.microsoft.com/en-us/library/windowsazure/hh974476.aspx
If you want to do authentication via AAD you can use the ADAL library:
http://msdn.microsoft.com/en-us/library/windowsazure/jj573266.aspx