bit.ly is not a reliable way to get usage statistics for a URL.
For best results, you should use the facilities provided by the web server itself.
Since you don't control bit.ly you can't control how they count hits.
I believe the QR Scanner program is performing a HEAD request instead of a GET request to validate the URL scanned. Since a HEAD will return re-direct information and is not (and should not be) counted in "hit" statistics you wouldn't see the hit on the bit.ly statistics.
While frustrating for your goals, this is one of the features that make QR Scanner better than other programs, you don't want to do a full GET when a HEAD will work.