In first step, You have to consider one table as master table which contains details about only books, not related with counts.
Book ( id {system_generate}, name, isbn_10, isbn_13, author, category_id )
Category ( id, name )
Create another table to maintain details about copies of book. for eg BookPieces ( your choice to keep different name as comfortable to you ). I will suggest you to create some random alphanumeric value for each book ie each book should have some 5 to 6 unique character for identication. You can use those number for transaction and references rather than 105, 2045, 23654 etc.
BooksPieces ( id, book_id )
Category is used to filter the data among the whole bunch.
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